The men said they have been held in a Harare prison for a year awaiting deportation after they asked to be allowed to form a "church to worship Satan" at a refugee camp in south-eastern Zimbabwe.
They became official refugees after fleeing civil war and persecution in their vast, central African country.
Zimbabwe is predominantly Christian and Satanism is not recognised as a legal faith.
Prison officials said they are in a quandary over the fate of the Satanists who are sowing fear among prison inmates and staff.
The two cannot be deported unless the UN revokes their refugee status.
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